Heck Reactions: A Caveat on the Use of Palladium(II) PCP‐Type Catalysts.
2010
Abstract A PCP-type catalyst was prepared and examined within the context of intramolecular Heck reactions. A substrate possessing a 1,4-diene system effectively poisoned the PCP catalyst leading to no reaction. This behavior contrasts with the typical palladium(0) catalyst system.
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