Experiments Directed Towards the Synthesis of Anthracyclinones. XXI. Claisen Rearrangements of Some Mixed Allyl Ethers

Da Beauregard,Rc Cambie,Kc Higgs,Peter S. Rutledge,Paul D. Woodgate

Experiments Directed Towards the Synthesis of Anthracyclinones. XXI. Claisen Rearrangements of Some Mixed Allyl Ethers

1994

Da Beauregard
Rc Cambie
Kc Higgs
Peter S. Rutledge
Paul D. Woodgate

Reductive Claisen rearrangement of mixed 1,4- and 1,5-bisallyl anthraquinone ethers has been investigated. The resulting C- allylated compounds have been converted into intermediates for use in anthracyclinone synthesis.

Keywords:

Biocatalysis
Anthraquinone
Inorganic chemistry
Organic chemistry
Catalysis
Reaction mechanism
Chemistry
Claisen rearrangement
Macromolecule
Supramolecular chemistry
Green chemistry

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