Precipitation and evolution of grain boundary boride in a nickel-based superalloy during thermal exposure

Abstract As a grain boundary strengthening element, B is widely applied in most Ni-based superalloys. However, the added B prefer to interact with other elements near the grain boundary and form borides which would perform evolution during high temperature service, and then affect the grain boundary strength and mechanical properties of the superalloy. In the present research, a trace B doped nickel-based IN792 superalloy was fabricated and preheat treated as 1120 °C/2 h AC + 1080 °C/4 h AC (AC: air cooling) followed by thermal exposure at 750 °C, 845 °C, 900 °C and 950 °C for different times to investigate the precipitation and evolution of grain boundary M 5 B 3 boride. The results indicate that M 5 B 3 boride precipitates along the grain boundary at the early time of the thermal exposure of IN792 superalloy. When thermal exposed at different temperatures, the grain boundary M 5 B 3 boride exhibits different evolution behavior. At 750 °C and 845 °C, M 5 B 3 boride grows up gradually with the thermal exposure proceeding, and no phase transformation occurs. While at 900 °C and 950 °C, the grain boundary M 5 B 3 boride precipitates at the early stage of the exposure process, and then transforms into M 23 C 6 carbide as gray film with the increasing of the exposure time.