SYNTHESIS OF CYCLOHEXAPYRROLIZIDINES- C-METHYLATION OF VINYLOGOUS AMIDES
1978
A synthesis of the cyclohexapyrrolizidines 32 and 33 is described; the structure of the latter was determined by X-ray crystallography. It is anticipated that this synthesis will serve as a model for the construction of a similar pyrrolizidine system during a projected synthesis of thelepogine 2.A convenient method for the C-methylation of cyclic vinylogous amides is also described. This procedure, which is similar to published procedures, affords high yields of methylated product and is regiospecific.
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