Derivative of oxygafluorene and di-tert-butyl carbazole as the host with very high hole mobility for high-efficiency blue phosphorescent organic light-emitting diodes
2016
Abstract Derivative of oxygafluorene and di- tert -butyl carbazole was synthesized as the host material for high-efficiency blue phosphorescent organic light-emitting diodes. It exhibited moderate thermal stability with 5% weight loss temperature of 337 °C and glass-forming ability with the glass-transition temperature of 65 °C. The solid-state ionization potential of di- tert -butyl carbazolyl-substituted oxygafluorene was found to be 5.54 eV as established by electron photoemission spectrometry. It showed low-dispersity hole transport with time-of-flight hole mobilities of 10 −2 cm 2 V −1 s −1 observed at high electric fields. Blue devices based on the synthesized compound showed high external quantum efficiency up to 16.5% and low efficiency roll-off.
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