Synthesis, structure, and magnetic properties of fluoride-bridged copper(II) dimers. Crystal and molecular structures of bis(.mu.-fluoro)bis[tris(3,4,5-trimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate) and bis(.mu.-fluoro)bis[(5-methylpyrazole-N2)bis(3,5-dimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate)

Frederik J. Rietmeijer,R.A.G. de Graaff,J. Reedijk

Synthesis, structure, and magnetic properties of fluoride-bridged copper(II) dimers. Crystal and molecular structures of bis(.mu.-fluoro)bis[tris(3,4,5-trimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate) and bis(.mu.-fluoro)bis[(5-methylpyrazole-N2)bis(3,5-dimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate)

1984

Frederik J. Rietmeijer
R.A.G. de Graaff
J. Reedijk

(I) cristallise dans P2 1 /n avec Z=2; affinement jusqu'a R=0,033. (II) cristallise dans P2 1 /c avec Z=2; affinement jusqu'a R=0,035. Geometrie approximativement pyramide a base carree dans les deux cas. Comparaison a des dimeres complexes de Cu(II) apparentes. Mesures de susceptibilite magnetique jusqu'a 2K. Spectres RPE

Keywords:

Photochemistry
Molecule
Copper
Tetrafluoroborate
X-ray crystallography
Inorganic chemistry
Tris
Chemistry
Fluoride
Magnetic susceptibility
Inorganic compound
Crystal structure

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