The Remarkable Effect of the 7-Substituent in the Diastereoselective Oxidative Rearrangement of Indoles: Asymmetric Synthesis of 3,3-Disubstituted Oxindoles.

Mathilde Lachia,Cyril Poriel,Alexandra M. Z. Slawin,Christopher J. Moody

The Remarkable Effect of the 7-Substituent in the Diastereoselective Oxidative Rearrangement of Indoles: Asymmetric Synthesis of 3,3-Disubstituted Oxindoles.

2007

Mathilde Lachia
Cyril Poriel
Alexandra M. Z. Slawin
Christopher J. Moody

The nature of the 7-substituent has a remarkable effect on the diastereoselectivity of the oxidative rearrangement of indole-2-carboxamides derived from (S)-2-methoxymethylpyrrolidine into chiral 3,3-disubstituted oxindoles.

Keywords:

Enantioselective synthesis
Oxidative phosphorylation
Substituent
Chemistry
Organic chemistry

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