Synthesis and crystal structure of a new inorganic-organic hybrid complex [Zn(4,4′-bipy)(2,2′-dpa)]_n

A new three-dimensional inorganic-organic hybrid complex:[Zn(4,4′-bipy)(2,2′-dpa)]n,was synthesized by mild hydrothermal techniques,and the crystal structure was determined.The complex crystallized in the monoclicnic space group C 2/c,with a=2.0178(4) nm,b=0.95049(19) nm,c=1.1421(2) nm,α=90°,β=117.11(3)°,γ=90°,V=1.9498(7) nm3,Z=8,R1=0.0439,wR2=0.1307.