Ligand-assisted nucleophilic additions. Control of site and face attack of nucleophiles on 4-oxido enones

Mark. Solomon,W. Charles L. Jamison,Michael S. McCormick,Dennis C. Liotta,David A. Cherry,John E. Mills,Rekha D. Shah,James Rodgers,Cynthia A. Maryanoff

Ligand-assisted nucleophilic additions. Control of site and face attack of nucleophiles on 4-oxido enones

1988

Mark. Solomon
W. Charles L. Jamison
Michael S. McCormick
Dennis C. Liotta
David A. Cherry
John E. Mills
Rekha D. Shah
James Rodgers
Cynthia A. Maryanoff

Les auteurs ont demontre qu'un haut degre de regioselectivite et de stereoselectivite peut etre atteint par l'utilisation d'un intermediaire alcoolate dans les additions nucleophiles

Keywords:

Nucleophile
Nucleophilic addition
Quinone
Alkoxide
Regioselectivity
Enone
Chemistry
Stereoselectivity
Photochemistry
Inorganic chemistry
Organic chemistry
Ligand
Stereochemistry

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