Synthesis of Quinolines from the Baylis-Hillman Acetates via the Oxidative Cyclization of Sulfonamidyl Radical as the Key Step.
2010
Abstract Ethyl 3-quinolinecarboxylates 5 were synthesized in good to moderate yields from the Baylis–Hillman acetates 1 via the oxidative cyclization reaction of the N-tosylamidyl radical, which was generated from the rearranged tosylamide derivatives 2 by iodobenzene diacetate and iodine.
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