2‐[2‐(Diphenylphosphanyl)ethyl]pyridine (pyphos)
2012
[10150-27-3] C19H18NP (MW 291.33)
InChI = 1S/C19H18NP/c1-3-10-18(11-4-1)21(19-12-5-2-6-13-19)16-14-17-9-7-8-15-20-17/h1-13,15H,14,16H2
InChIKey = ARSGXAZDYSTSKI-UHFFFAOYSA-N
(ligand used in transition metal mediated reactions)
Physical Data: mp 58–62 °C.
Solubility: soluble in most organic solvents.
From Supplied in: white to tan solid, available from select catalog suppliers.
Preparative Methods: most commonly prepared by the reaction of 2-vinylpyridine and diphenylphosphine in the presence of acid,1 base,2 or transition metal3 catalysts.
Purification: chromatography or crystallization from alcohol-water mixtures.
Handling, Storage, and Precautions: to prevent oxidation material should be stored and handled under nitrogen.
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