Sulfonylgesubstitueerde methylesters van enkele sterke zuustofzuren. Synthese en solvolyse

The present study is concerned with the syntheses and the mechanisms of solvolysis of sulfonyl substituted methyl esters of three different types of strong oxygen acids, i. e . alkyl- and arylsulfonylmethylperchlorates, aryrsulfonylmethylnitrates and arylsulfonylmethyl arenesulfonates. These esters are readily accessible via the reaction of an q-diazosulfone and the appropiate acid in an aprotic solvent. The spectral data and some properties of these types of compounds are discussed. ... Zie: Summary