Highly Anisotropic Thermal Conductivity of Layer-by-Layer Assembled Nanofibrillated Cellulose/Graphene Nanosheets Hybrid Films for Thermal Management
2017
An anisotropic thermally conductive film with tailorable microstructures and macroproperties is fabricated using a layer-by-layer (LbL) assembly of graphene oxide (GO) and nanofibrillated cellulose (NFC) on a flexible NFC substrate driven by hydrogen bonding interactions, followed by chemical reduction process. The resulting NFC/reduced graphene oxide (RGO) hybrid film reveals an orderly hierarchical structure in which the RGO nanosheets exhibit a high degree of orientation along the in-plane direction. The assembly cycles dramatically increase the in-plane thermal conductivity (λX) of the hybrid film to 12.6 W·m–1·K–1, while the cross-plane thermal conductivity (λZ) shows a lower value of 0.042 W·m–1·K–1 in the hybrid film with 40 assembly cycles. The thermal conductivity anisotropy reaches up to λX/λZ = 279, which is substantially larger than that of similar polymeric nanocomposites, indicating that the LbL assembly on a flexible NFC substrate is an efficient technique for the preparation of polymeric n...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
77
References
188
Citations
NaN
KQI