Rutile Nanorod/Anatase Nanowire Junction Array as Both Sensor and Power Supplier for High‐Performance, Self‐Powered, Wireless UV Photodetector

Self-powered UV photodetectors based on TiO2 nanotree arrays have captured much attention in recent years because of their many advantages. In this work, rutile/anatase TiO2 (R/A-TiO2) heterostructured nanotree arrays are fabricated by assembling anatase nanowires as branches on rutile nanorods. External quantum efficiencies as high as 90% are reached at 325 nm. These high quantum efficiencies are related to the higher amount of light harvesting due to the larger surface area, the better separation ability of the photogenerated carriers by the rutile/anatase heterostructure, and the faster electron transport, related to the 1D nanostructure and lattice connection at the interface of the two kinds of TiO2. Furthermore, a self-powered wireless UV photodetector is shown with excellent wireless detection performance. Such devices will enable significant advances for next-generation photodetection and photosensing applications.