(Diacetoxyiodo)benzene-Mediated Oxygenation of Benzylic C(sp3)-H Bonds with N-Hydroxyamides at Room Temperature.

Peng‐Cheng Qian,Yu Liu,Ren-Jie Song,Ming Hu,Xu‐Heng Yang,Jian Nan Xiang,Jin‐Heng Li

(Diacetoxyiodo)benzene-Mediated Oxygenation of Benzylic C(sp3)-H Bonds with N-Hydroxyamides at Room Temperature.

2015

Peng‐Cheng Qian
Yu Liu
Ren-Jie Song
Ming Hu
Xu‐Heng Yang
Jian Nan Xiang
Jin‐Heng Li

A new and general, catalyst-free strategy for the formation of C(sp3)—O bonds is established by iodosobenzene diacetate-mediated oxygenation of benzylic C(sp3)—H bonds with N-hydroxyamides.

Keywords:

Iodosobenzene
Medicinal chemistry
Oxygenation
Hydroxylation
Benzene
Chemistry
Organic chemistry

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