A high-quality mechanofusion coating for enhancing lithium-ion battery cathode material performance
2019
Lithium (Li)-ion battery cathode materials are typically coated to improve cycling performance, using aqueous-based coating techniques that require filtering, drying, and even sintering of the final product. Here, spherical LiNi 0.6 Mn 0.2 Co 0.2 O 2 particles were coated with nano-Al 2 O 3 using the dry mechanofusion method. This method produced a durable, non-porous Al 2 O 3 coating that is retained during slurry making. Mechanofusion coatings significantly improved Li-ion battery cathode cycling at high voltages, enabling high energy densities, while offering inexpensive, scalable, and environmentally friendly solvent-free synthesis. This opens up new possibilities, since, not being limited by synthesis chemistry, mechanofusion can in principle be used to apply any coating material.
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