Detailed mineralogical-geochemical study of a large spinel Lherzolite xenolith in alkali basalt of Shavaryn Tsaram paleovolcano, Mongolia

Mineralogical-geochemical data obtained on a large xenolith of spinel lherzolite from basanites of Shavaryn Tsaram volcano (Middle Pleistocene) provide evidence that the xenolith was affected by heat and fluid that came from the basalt melt and induced geochemical heterogeneity of the xenolith. Olivine crystals from the central portion of the xenolith contain much more CaO than this mineral from the peripheral zones of the xenolith as well as in xenocrystals of the host basalts. The large xenolith was unevenly annealed by the host basalt melt, and this predetermined the heterogeneous diffusion-controlled “purification” of olivine crystals from their CaO admixture. The xenolith is heterogeneously enriched in LREE and some trace elements (Zr, Hf, Nb, Th, and U), and their distribution demonstrates unclearly pronounced concentric zoning: these elements enriched the outer portions of the xenolith. The enrichment of the xenolith in LREE and other mobile trace elements is explained by their occurrence not only as structurally bound (isomorphic) components in minerals but also in the form of nonstructural admixtures (contaminant), as minute grains of compounds hosted in the interstitial space and tiny cracks cutting mineral grains. The enrichment of the xenolith in these admixtures proceeded via their infiltration-controlled introduction with fluid from the basalt along minute cracks.