Moments of energy level distributions in vibrational spectra
1993
Expressions for moments of the spectral density distribution of a system described by a non-symmetric N-particle Hamiltonian are derived. In particular, this kind of Hamiltonian may represent N coupled oscillators; then its spectrum models the vibrational spectrum of a molecule. It is assumed that the Hamiltonian is defined in a finite-dimensional space formed by products of orthogonal eigenstates of some one-body Hamiltonians. Possible applications of the formalism are briefly discussed.
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