Kinetics and mechanism of hydrogenolysis of n-pentane on an alumoplatinum catalyst
1977
1.
Study has been made of the kinetics of hydrogenolysis and isomerization of n-pentane on an alumoplatinum catalyst at atmospheric pressure. The hydrogenolysis reaction follows a rational-fractional equation, and isomerization an exponential equation.
2.
A stepwise reaction scheme is proposed in which the limiting step for hydrogenolysis is the C-C bond rupture and that for isomerization transformation of the surface C5H11 fragments on carrier boundary acid centers through the action of the gas phase hydrogen.
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