Photoluminescent phenylated polyfluorenes synthesized in an organic solvent and supercritical carbon dioxide
2012
A number of new phenylated polyfluorenes with blue emission are synthesized via the Diels-Alder reaction in chloronaphthalene and supercritical carbon dioxide. It is shown that these polymers are thermally stable. A comparative analysis of their properties shows that a “green” solvent is a suitable alternative to organic solvents for obtaining phenyl-substituted polyfluorenes via the Diels-Alder reaction.
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