Ligand-Acceleration by a Chiral Modifier in the Enantioselective Hydrogenation of Methyl Acetoacetate on a Raney Nickel Catalyst: Effect of a Modifier Configuration

Takashi Sugimura,Satoshi Nakagawa,Naoya Kamata,Takahiro Tei,Takashi Tajiri,Ryo-Ichi Tsukiyama,Tadashi Okuyama,Yasuaki Okamoto

Ligand-Acceleration by a Chiral Modifier in the Enantioselective Hydrogenation of Methyl Acetoacetate on a Raney Nickel Catalyst: Effect of a Modifier Configuration

2015

Takashi Sugimura
Satoshi Nakagawa
Naoya Kamata
Takahiro Tei
Takashi Tajiri
Ryo-Ichi Tsukiyama
Tadashi Okuyama
Yasuaki Okamoto

Reaction rate and enantioselectivity of asymmetric hydrogenation of methyl acetoacetate were studied over Raney nickel catalysts modified with (R,R)-tartaric acid, malic acid, or succinic acid to r...

Keywords:

Enantioselective synthesis
Raney nickel
Inorganic chemistry
Methyl acetoacetate
Organic chemistry
Chirality (chemistry)
Catalysis
Ligand
Chemistry
Malic acid
Succinic acid
Asymmetric hydrogenation

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