Magnetic susceptibility of antiferromagneticIr4+complexes

1974 
Magnetic susceptibility in the antiferromagnetic and the paramagnetic phase is calculated by using a molecular-field model, wherein the molecular field is calculated self-consistently. When applied to the hexachloroiridates, it is shown that the observed and the calculated susceptibility in the antiferromagnetic phase agree well. As in the case of rareearth compounds, this model is adequate to treat the crystal-field effects in the compounds of the transition-metal ions.
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