Role of Bimolecular Exciton Kinetics in Controlling the Efficiency of Organic Light-Emitting Diodes

Here, we have carried out a spectroscopic investigation on the operational organic light-emitting diodes (OLEDs) to determine the role of emission layer thickness on the optoelectronic performance of OLEDs based on a poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT) copolymer system. Our study shows that delayed fluorescence (DF) via triplet–triplet annihilation (TTA) contributes significantly to boost the OLED efficiency through its fractional contribution. Interestingly, we note that DF contribution varies as a function of the emissive layer thickness. From the time-resolved electroluminescence (TREL) and triplet absorption (under electrical excitation) studies, we have seen that the emissive layer thickness controls triplet exciton generation and decay processes. From TREL, we have also shown that singlet–triplet annihilation (STA) is the dominant fluorescence quenching mechanism in bulk of the emissive layer, whereas thinner devices have significant exciton quenching at the interface of the inject...