Influence of Phase Separation on Performance of Graft Acrylic Pressure-Sensitive Adhesives with Various Copolyester Side Chains

Acrylic pressure-sensitive adhesives with various polyester side-chain lengths were synthesized to investigate the effect of branching on phase separation and polymer mechanical performance. The polyester macromonomers (MMs) were produced through ring-opening co-polymerizations of l-lactide (l-LA) and e-caprolactone (e-CL) initiated with 2-hydroxyethyl methacrylate (HEMA), which provides the polyester chains with terminal vinyl groups. By varying the HEMA content, a range of MM chain lengths constructed from L10C4 (five l-LA and four e-CL units) to L100C40 were obtained at a constant monomer mole ratio. Copolymerization of 2-ethylhexyl acrylate and acrylic acid with these MMs at constant mass composition provided a series of comb copolymers consisting of acrylic backbones with polyester branches of various chain lengths. Characterization of thin films cast from the polymers using thermal analysis and scanning probe microscopy showed a transition from a homogeneous phase to the formation of distinct microp...