Highly efficient and thermal stable La2Si2O7:Ce3+,Tb3+,Eu3+ phosphors: Emission color tuning through terbium bridge

Abstract A series of emission color tunable Ce 3+ , Tb 3+ , and Eu 3+ co-doped La 2 Si 2 O 7 (LSO) phosphors have been prepared via a solid state reaction. The crystal structure, luminescence properties, and thermal stability of the phosphors were studied in this paper. There exists two kinds of energy transfer (ET) modes under UV excitation, namely, electric dipole-dipole interaction for Ce 3+ →Tb 3+ and terbium bridge model [Ce 3+ →(Tb 3+ ) n →Eu 3+ ] for LSO:Ce 3+ ,Tb 3+ ,Eu 3+ system. The emitting color of the phosphors can be tuned from green to yellow and eventually to orange-red through the Ce 3+ →Tb 3+ →Eu 3+ energy transfer. Although codoping Tb 3+ and Eu 3+ into La 2 Si 2 O 7 :Ce 3+ leads to the reduction of thermal stability, it still remains 80% for LSO:0.05Ce 3+ ,0.8 Tb 3+ ,0.02Eu 3+ at 150 °C when compared to that at room temperature. The absolute quantum yield (QY) increases from 71.04% (LSO:0.05Ce 3+ ) to 95.60% (LSO:0.05Ce 3+ , 0.6 Tb 3+ ), while those of LSO:0.05Ce 3+ , y Tb 3+ ,0.02Eu 3+ samples remain more than 70%. These results indicate that the phosphors can be candidates for application in phosphor-converted white light-emitting diodes (pc-WLEDs).