Hydrothermal synthesis of BaLu2F8:Ln3+ crystals: Phase/ morphology evolution, energy transfer and tunable multicolor luminescence

BaLu2-xF8: xLn3+ crystals have been synthesized via a one-step hydrothermal route without any surfactants. X-ray diffraction (XRD), scanning electron microscopy (SEM), and down–shift/up-conversion photoluminescence spectra were used to characterize the samples. The pure monoclinic BaLu2F8 crystals were obtained at pH = 7 with the NaBF4 as fluoride source. Doping 0.06 mmol Ln3+ ions from Ho3+ to La3+ and doping Yb3+ ions from 0.1 to 0.4 mmol both have caused dramatic changes to product’s morphology from prismatic microrods about 10 μm to particles about 3 μm aggregated by flakes. The different phase, size and shape of final product greatly related to fluoride source and pH values, which have been studied in detail. In addition, the surfactants also affected the phase and morphology of the BaLu2F8 crystals. The multicolor down–shift emission was achieved in the BaLu1.94F8: 0.06Ln3+ (Ln = Sm, Eu, Tb, Dy, Er and Tm) crystals under excitation at 365 nm UV lamp; and the multicolor UC luminescence has been achieved in BaLu2F8: Yb3+, Ln3+ (Ln = Er, Tm, Ho) systems. When the Yb3+-Er3+ ions co-doped in host, the mechanism for the red emission (4F9/2  4I15/2) retains the tri-photon process like the single-doped Er3+ ion, but the mechanism for the green emission (2H11/2/4S3/2  4I15/2) is a two-photon process. Furthermore, the UC luminescence mechanism for the co-doping Yb3+-Ho3+ pairs is also a tri-photon process in the BaLu2F8 matrix. The as-prepared BaLu2F8:Ln3+ phosphors have potential applications in the fields of light emitting device, three- dimensional display and backlighting.