Determination and stability of phenmediphan, ethofumesate and fenamiphos in ground water samples using automated solid phase extraction cartridges followed by liquid chromatography high flow pneumatically assisted electrospray mass spectrometry

Abstract The determination and stability of polar pesticides phenmediphan, ethofumesate and fenamiphos in ground water samples was subjected to analysis with solid phase extraction (SPE) followed by liquid chromatographyhigh flow pneumatically assisted electrospray mass spectrometry (LC-ESP-MS). Pesticides were spiked at 6 μg/L in ground water samples and 80 mL were preconcentrated by using an Automated Sample Preparation with Extraction Columns (ASPEC XL) system. After preconcentration, several different storage conditions were tested, which included storage at 4[ddot]C, at −20[ddot]C and at room temperature using styrene divinylbenzene (SDB) cartridges. The percentage of degradation varied from 20 to 80% for all the studied pesticides after 20 days of storage at room temperature. Phenmediphan and ethofumesate were stable at 4[ddot]C and −20[ddot]C during all the studied period whereas fenamiphos was recovered only 32 and 50% at 4 [ddot]C and −20[ddot]C, respectively, after 80 days of storage. The L.O.D ...