Synthesis and Diels–Alder Reactions of 3‐Acetyl‐2(3H)‐oxazolone: 6‐Amino‐3,4‐dimethyl‐cis‐3‐cyclohexen‐1‐ol
2003
Synthesis and Diels–Alder reactions of 3-acetyl-2(3H)-oxazolone: 6-amino-3,4-dimethyl-cis-3-cyclohexen-1-ol
intermediate: 326 g (3.75 mol) of 2-oxazolidinone
intermediate: 258 g (2.0 mol) of 3-acetyl-2-oxazolidinone
intermediate: 4-Acetyl-7,8-dimethyl-2-oxa-4-azabicyclo[4.3.0]non-7-en-3-one.
product: 63.5 g (0.5 mol) of 3-acetyl-2(3H)-oxazolone
product: 6-Amino-3,4-dimethyl-cis-3-cyclohexen-1-ol.
Keywords:
acylation;
annulation, carbocyclic-[6];
cyclization, condensation;
cyclization, cycloaddition;
Diels-Alder reactions;
elimination, dehydrohalogenation;
halogenation, chlorination;
hydrolysis, miscellaneous;
photochemical reactions;
autoclaves and pressure reactors, autoclave, for Diels-Alder reaction;
photochemical apparatus, lamps, photochemical;
pressure vessel;
pressure vessel
Keywords:
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