Calorimetric study of the inhibition of runaway reactions during methylmethacrylate polymerization processes

Reaction inhibition was adopted as a method to halt runaway phenomena during polymerization experiments. Use of reaction calorimetry coupled with a particular system for early detection of the onset of runaway (early warning detection system) has allowed to investigate the behaviour of two substances that can influence the reaction rate: hydroquinone and 1,4-benzoquinone. The process studied was the free-radical polymerization of methylmethacrylate carried out under batch conditions in bulk or in emulsion. The results show that hydroquinone and 1,4-benzoquinone behave differently: the first is an inhibitor because it completely stops the process; the second behaves as a retarder and could be used industrially to control the process and keep the reactor temperature within safe limits.