Cellulose Nanofibrils and Diblock Copolymer Complex: Micelle Formation and Enhanced Dispersibility
2017
A great challenge to the utilization of bioderived cellulose nanofibrils (CNFs) is related to dispersion, where the hydrophilic nature makes them difficult to disperse in both organic solvents and hydrophobic polymers. In this study, an amphiphilic diblock copolymer, poly(methyl methacrylate-b-acrylic acid) (PMMA-b-PAA), which contains a short interactive block of PAA and a long hydrophobic block of PMMA, was utilized to modify the surface of CNFs covered with carboxylic acid groups (CNF-COOH). The PAA block binds to the surface carboxylic acid groups on the CNFs through the formation of multiple hydrogen bonds, while the hydrophobic PMMA block enables better dispersion of the CNFs as well as interfacial adhesion with the matrix polymer. The attachment of PMMA-b-PAA to the CNFs was confirmed through Fourier transform infrared spectroscopy. Micelles were observed to form from a dispersion of CNF-COOH/PMMA-b-PAA complex in H2O. Good dispersion with individualized nanofibrils has been achieved in dimethylfor...
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