Comparison study of electrocatalytic activity of reduced graphene oxide supported Pt–Cu bimetallic or Pt nanoparticles for the electrooxidation of methanol and ethanol

Abstract Pt–Cu bimetallic nanoparticles supported on reduced graphene oxide (Pt–Cu/RGO) were synthesized through the simple one-step reduction of H 2 PtCl 6 and CuSO 4 in the presence of graphene oxide (GO) at room-temperature. The Pt–Cu/RGO was characterized with UV–vis spectrophotometer, X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy and its catalytic behavior for the direct oxidation of methanol was investigated. Compared to Pt/RGO and Pt/C catalysts, Pt–Cu/RGO hybrids exhibited markedly superior catalytic activity for the electrocatalytic oxidation of methanol and ethanol. This improved catalytic activity can be attributed to the dendritic structure of the Pt–Cu bimetallic nanoparticles.