A photo-capacitive sensor operational from 6 K to 350 K with a solution printable, thermally-robust hexagonal boron nitride (h-BN) dielectric and conductive graphene electrodes
2020
Abstract A new exfoliation route is introduced for overcoming the drawback of horn-tip exfoliation by combining it with slow magnetic stirring for hexagonal boron nitride (h-BN) bulk crystals. Inkjet printing of h-BN is then conducted, where various patterns were designed and printed and a change from translucent-to-opaque was observed with increasing printing passes from 1 pass (0.417 µm thickness) to 5 passes (1.964 µm thickness). The increase in the E2g peak intensity in the Raman spectra with the thickness of h-BN printed films is demonstrated, which is attributed to an increase in collective photon number as thickness increases. The effect of temperature on the Raman spectra of printed h-BN patterns is studied and the first-order temperature coefficient χ is derived indicative of the thermal properties of printed h-BN films at elevated temperatures. The red-shift of the E2g peak with temperature arises from the variation in the interplanar vibrational frequency with material expansion due to heating. The χ values of −0.033 cm−1/K and −0.028 cm−1/K for 20 and 30 passes of printed h-BN is suggestive of thermally stable h-BN after annealing. All inkjet-printed graphene/h-BN/graphene capacitors were fabricated and the leakage current density, JLeakage, was measured to be ∼ 72 nA/mm2, while the capacitance density was measured to be ∼ 2.4 µF/cm2. Finally, the influence of temperature, frequency, and light irradiation on the performance of graphene/h-BN-based capacitive structures were explored using capacitance density-voltage measurements. The ratio, Con/Coff, between the capacitance density in the illumination ON state, Con, and in the illumination OFF or dark state, Coff, was also calculated for the graphene/h-BN capacitor fabricated with 30 printing passes. The Con/Coff was ∼ 1.6 at 6 K and ∼ 1.4 at 350 K (measured at 1 kHz frequency), suggesting the potential of this 2D graphene/h-BN heterostructure to serve as a photo-capacitive sensing element for printed electronics applications over a wide thermal regime from 6 K to 350 K.
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