Improvement of stability of n-type super growth CNTs by hybridization with polymer for organic hybrid thermoelectrics

Abstract In order to fabricate effective Π-form thermoelectric devices both positive-type (p-type) and negative-type (n-type) semiconductors are expected to be used for the fabrication. There are a few reports on n-type organic thermoelectric materials and they are usually unstable in air. Here, we report the considerable stabilization of n-type carbon nanotubes/hydrazine hybrid films by mixing a common polymer, poly(vinyl chloride) (PVC) and poly(vinylidene difluoride) (PVDF). The n-type carbon nanotubes were synthesized by dispersion of super growth carbon nanotubes (SG-CNTs) into hydrazine hydrate in NMP ( N -methyl-2-pyrrolidone). The SG-CNT/Hydrazine/PVC hybrid films were fabricated by a simple method to drop-cast the mixtures on a glass substrate. To evaluate the air durability of SG-CNT/Hydrazine/PVC hybrid film, the samples were kept in air and the temporal change of the thermoelectric properties in air was measured. After 150 min Seebeck coefficients of n-type SG-CNT without polymer changed from −5.0 μV K −1 to 7.0 μV K −1 . On the other hand, the SG-CNT/Hydrazine/PVC hybrid films were rather stable in air and kept negative Seebeck coefficient even after 28 days.