Solvent vapor annealing of oriented PbI2 films for improved crystallization of perovskite films in the air

Abstract The photovoltaic performance of perovskite solar cells is extremely dependent on the crystallization and morphology of the perovskite film, which are affected by the deposition method. Here, we demonstrate a simple approach to form a microporous PbI 2 film, with subsequent conversion to a compact, highly crystalline perovskite film. The PbI 2 and corresponding perovskite films were further probed by two-dimensional X-ray diffraction. The resultant perovskite exhibited improved photovoltaic performance under ambient conditions with about 50% humidity. The PbI 2 microporous structure was formed by exchanging residual DMSO with DMF vapor in the PbI 2 film, which facilitated contact with the methylammonium iodide (MAI) solution. The process resulted in the formation of compact, smooth, pinhole-free perovskite films having no residual PbI 2 . Solar cells fabricated using this methodology exhibited power conversion efficiencies over 16% with negligible photocurrent hysteresis.