Synthesis and $\textit{in-situ}$ characterization of photochromic yttrium oxyhydride grown by reactive $e^-$-beam evaporation.

We report on controlled growth of photochromic yttrium oxyhydride ($YH_xO_y$) thin films monitored by $\textit{in-situ}$ composition depth profiling. Films were grown by reactive $e^-$-beam evaporation and subsequently oxidized, while simultaneously tracking the oxygen and hydrogen concentrations. Sample composition and photochromic response were characterized $\textit{in-situ}$ using non destructive ion beam analysis and image analysis, respectively - as well as complementary $\textit{ex-situ}$ ion beam methods, X-ray diffraction and optical spectrophotometry. We show that photochromic yttrium oxyhydride ($YH_xO_y$) can be grown as $YH_2$, which is then oxidized to O/H ratios triggering the photochromic response.