Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

Benjamin M. Gridley,Toby J. Blundell,Graeme J. Moxey,William Lewis,Alexander J. Blake,Deborah L. Kays

Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

2013

Benjamin M. Gridley
Toby J. Blundell
Graeme J. Moxey
William Lewis
Alexander J. Blake
Deborah L. Kays

The reaction between sterically demanding m-terphenyl lithiate complexes and cadmium dihalides yields unusual cubanes where changes in ligand bulk afford different formulations, in particular a rare heterodicubane structure.

Keywords:

Steric effects
Terphenyl
Inorganic chemistry
Chemistry
Photochemistry
Cadmium
Ligand
Organic chemistry
Cubane

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