Efficient Desymmetrization of 1,2- and 1,3-Diols by Dimethyldioxirane.
1995
Abstract Dimethyldioxirane was used to monooxidize 1,2 and 1,3 sec,sec-diols to the corresponding ketoalcohols, exploiting the inhibiting effect of the formed carbonyl group on the course of the process.
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