Supercooled Water Drops Do Not Freeze During Impact on Hybrid Janus Particle-Based Surfaces

Icing of various surfaces is often a result of the collision of supercooled water drops with substrates. Ice formation from supercooled water drops is initiated by nucleation when the size of an ice embryo reaches a critical value. The lack of controlling the inception of heterogeneous nucleation and the rate of solidification, which depend on the properties of the substrate, temperature, and impact parameters of the liquid drop, poses a very serious challenge to the design of effective ice-preventing materials. In this exploratory experimental study, we show how a significant nucleation delay during impact of supercooled water drops can be achieved by tuning the properties of the substrate and, specifically, by introducing chemical and topographical heterogeneities on the surfaces formed by a mixture of either polymer-coated hydrophilic and hydrophobic particles or Janus particles. We have discovered that the nucleation rate during drop impact is significantly reduced on heterogeneous surfaces formed by ...