Dendritic azo compounds as a new type amorphous molecular material with quick photoinduced surface-relief-grating formation ability

Abstract A series of dendritic azobenzene-containing compounds have been synthesized as a new type amorphous molecular material, which can show quick surface-relief-grating (SRG) formation ability upon light irradiation. For the synthesis, the dendritic precursor tris (2-(ethyl(phenyl)amino)ethyl)benzene-1,3,5-tricarboxylate and tris (3,5-bis(2-(ethyl(phenyl)amino)ethoxy)benzyl)benzene-1,3,5-tricarboxylate were prepared by esterification reactions between 1,3,5-benzenetricarbonyl chloride and N -ethyl- N -hydroxyethyl-aniline and 3,5-bis[2-( N -ethylanilino)ethoxy] benzylalcohol. The precursors were, respectively reacted with the diazonium salts of 4-nitroaniline, 4-aminobenzoic acid, and 4-aminobenzonitrile to introduce different types of donor–acceptor azo chromophores at the peripheral positions. The structure and properties of the dendritic azo compounds were characterized by the spectroscopic methods and thermal analysis. The surface-relief-grating (SRG) formation behavior of the dendritic azo compounds was studied by exposing the spin-coated thin films to an interference pattern of laser beams (532 nm) at modest intensity (100 mW/cm 2 ). The results show that the azo compounds can form stable amorphous glasses in a broad temperature range. The glass transition temperatures ( T g s) depend on the backbone structures and the type of the peripheral azo chromophors. The type of the electron withdrawing groups in the p -positions of the terminal azobenzene units shows a significant influence on the SRG inscription rate. For the compounds containing the same type azo chromophores, the SRG inscription rate is also affected by the backbone structure.