Effects of Strong Electronic Coupling in Chlorin and Bacteriochlorin Dyads
2016
Achieving tunable, intense near-infrared absorption in molecular architectures with properties suitable for solar light harvesting and biomedical studies is of fundamental interest. Herein, we report the photophysical, redox, and molecular-orbital characteristics of nine hydroporphyrin dyads and associated benchmark monomers that have been designed and synthesized to attain enhanced light harvesting. Each dyad contains two identical hydroporphyrins (chlorin or bacteriochlorin) connected by a linker (ethynyl or butadiynyl) at the macrocycle β-pyrrole (3- or 13-) or meso (15-) positions. The strong electronic communication between constituent chromophores is indicated by the doubling of prominent absorption features, split redox waves, and paired linear combinations of frontier molecular orbitals. Relative to the benchmarks, the chlorin dyads in toluene show substantial bathochromic shifts of the long-wavelength absorption band (17–31 nm), modestly reduced singlet excited-state lifetimes (τS = 3.6–6.2 ns vs...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
57
References
18
Citations
NaN
KQI