Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)–Ru(III) Dimer Coupling

Olga Impert,Anna Kozakiewicz,Grzegorz Wrzeszcz,Anna Katafias,Alina Bieńko,Rudi van Eldik,Andrew Ozarowski

Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)–Ru(III) Dimer Coupling

2020

Olga Impert
Anna Kozakiewicz
Grzegorz Wrzeszcz
Anna Katafias
Alina Bieńko
Rudi van Eldik
Andrew Ozarowski

In this contribution, we report the synthesis and full characterization of the first mixed-valence Ru(II)/Ru(III) ion-pair complex, [RuII(bipy)2(pic)]+[cis-RuIIICl2(pic)2]−, in the solid state and ...

Keywords:

Coupling
Crystallography
Valence (chemistry)
Photochemistry
ion pairs
Electron paramagnetic resonance
Dimer
Solid-state
Chemistry

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations