Reaction of benzyne with 1,2,3,4-tetrahydroisoquinolines as an access to 1H-3-benzazepines

2018 
1,2,3,4-Tetrahydroisoquinolines bearing phenacyl group at the nitrogen atom in their reaction with benzyne in acetonitrile undergo ring expansion to give 1 H -3-benzazepines.
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