Preliminary calibration results of VEGA 1 and 2 SIGMA-3 gas chromatograph

Abstract SIGMA - 3 gas chromatograph on board VEGA 1 and 2 landing probes has been operated successfully in the ∼ 60 - 50 km altitude range, providing several in - situ chemical analysis of the gas and the aerosols of Venus cloud layers. Post flight calibration required to derive atmospheric abundancies from gas chromatograms were carried out using the SIGMA - 3 spare model. A Venus atmospheric aerosol simulation chamber was used in which sulfuric acid droplets were generated. Preliminary results of these calibration experiments indicate that the concentration of sulfuric acid in the upper part of the clouds (∼ 60 to 55 km) is about 1 mg/m 3 and suggest that an additional constituant must be present in noticeable amount in the aerosols. From these experiments the mixing ratio upper limits of SO 2 is 100 ppmV and of H 2 S and COS is few 10 ppmV.