Removal kinetics of phosphorus from synthetic wastewater using basic oxygen furnace slag.

Abstract Removal kinetics of phosphorus through use of basic oxygen furnace slag (BOF-slag) was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial pH, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant ( k obs ) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial pH, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage. A linear dependence of k obs on total removed phosphorus (TRP) was established with k obs  = (3.51 ± 0.11) × 10 − 4  × TRP. Finally, it was suggested that the Langmuir–Rideal (L–R) or Langmuir–Hinshelwood (L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag.