Multiple Alignment Modes for Nematic Liquid Crystals Doped with Alkylthiol-Capped Gold Nanoparticles

The ability of alkylthiol capped gold nanoparticles (Au NPs) to tune, alter, and reverse the alignment of nematic liquid crystals (LCs) has been investigated in detail. Adjusting the concentration of the suspended Au NPs in the nematic LC host, optimizing the sample preparation protocol, or providing different sample substrates (untreated glass slides, rubbed polyimide-coated LC test cell, or ITO-coated glass slides) results in several LC alignment scenarios (modes) including vertical alignment, planar alignment, and a thermally controlled alignment switch between these two alignment modes. The latter thermal switch between planar and homeotropic alignment was observed particularly for lower concentrations (i.e., around 1 to 2 wt %) of suspended NPs in the size regime of 1.5−2 nm and was found to be concentration-dependent and thermally reversible. Different scenarios are discussed that could explain these induced alignment modes. In one scenario, the NP-induced alignment is related to the temperature-dep...