Exciton polariton in an organic–inorganic multiple-quantum-well crystal (C4H9NH3)2PbBr4

Abstract Exciton polariton in an organic–inorganic multiple-quantum-well (MQW) single crystal (C 4 H 9 NH 3 ) 2 PbBr 4 at low temperature has been investigated by photoluminescence excitation (PLE), reflection, and time-resolved photoluminescence measurements. Since (C 4 H 9 NH 3 ) 2 PbBr 4 has ideal two-dimensional excitons with an extremely large oscillator strength and forms self-organized MQW with a very short well-period ( d ∼10 A), polaritonic coupling among excitons is strong and extends over a large number of wells. Therefore, observed MQW polariton features were the same as those of bulk polaritons. We have also investigated relaxation dynamics of the MQW polariton in the same framework as discussions on bulk polaritons.