Synthesis and Properties of Methano-Bridged Tetradehydro-(26)-, -(28)-, -(30)-, -(32)-, -(34)-, and -(38)-annulene.
1988
Title annulenes (21)–(28) have been synthesized by a Wittig reaction of 1,6-bis-(4-formylbuta-1,3-dienyl)cyclohepta-1,3,5-triene (5) and the vinylogous dicarbaldehydes (6)–(10) with 3-methylpent2-en-4-ynyl(triphenyl)phosphonium bromide (11) or triphenyl-(3-t-butylpent-2-en-4-ynyl)phosphonium bromide (12), followed by intramolecular oxidative coupling of the resulting acyclic diacetylenes, and their properties are discussed on the basis of 1H n.m.r. and electronic spectra.
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