Synthesis and chemistry of a very stable but reactive diisocyanate, trioxabicyclo[3.3.1]nonadiene diisocyanate
2012
The bisdioxine diisocyanate 5 is exceptionally stable, being formed readily in Curtius and Hofmann rearrangements. It does not hydrolyze easily but forms diurea and diurethane derivatives in high yields.
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