Iron-catalyzed tandem cyclization of olefinic dicarbonyl compounds with benzylic Csp3–H bonds for the synthesis of dihydrofurans
2015
A novel iron-catalyzed radical cyclization of olefinic dicarbonyl compounds with benzyl hydrocarbons has been developed. This protocol provides ready access to a variety of dihydrofurans containing a quaternary carbon center in moderate to good yields. Furthermore, this reaction could also be further expanded to other types of substrates containing unactivated Csp3–H bonds, such as ethers and alkanes.
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