Low-Pressure-Assisted Coating Method To Improve Interface between PEDOT:PSS and Silicon Nanotips for High-Efficiency Organic/Inorganic Hybrid Solar Cells via Solution Process

Nanostructured silicon hybrid solar cells are promising candidates for a new generation photovoltaics because of their light-trapping abilities and solution processes. However, the performance of hybrid organic/Si nanostructure solar cells is hindered because of carrier recombination at surface and poor coverage of organic material poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) on nanostructures. Here we demonstrate low-pressure-assisted coating method of PEDOT:PSS on surface-modified silicon nanotips with broadband light-trapping characteristics to improve interface property and to achieve high-efficiency hybrid solar cells through a solution process. The approach enhances the effective minority-carrier lifetime and the coverage of PEDOT:PSS on the surface of nanostructures. Hybrid solar cells fabricated with surface-modified nanotips exhibit a high fill factor of 70.94%, short-circuit current density of 35.36 mA/cm2, open-circuit voltage of 0.528 V, and power conversion efficiency o...